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http://hdl.handle.net/1842/3016
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| Title: | Synthesis and structural characterisation of an yttrium-alkyl-alkylidene |
| Authors: | Arnold P.L.
Green J.C.
McMaster J.
Liddle S.T. |
| Issue Date: | 1-Apr-2008 |
| Citation: | Arnold P.L., Green J.C., McMaster J., Liddle S.T.. (2008-04-01) Synthesis and structural characterisation of an yttrium-alkyl-alkylidene, Chemical Communications 15 1747-1749 |
| Abstract: | The first structurally authenticated yttrium-alkyl-alkylidene is reported; structural, spectroscopic, and theoretical analyses show that whilst the yttrium-alkylidene bond is short, it possesses a bond order less than one and is comparable to the Y-C-alkyl single bond within the same molecule. |
| Keywords: | metal-carbon bonds; x-ray structures; nobel lecture; olefin-metathesis; transition-metal; carbene complex; reactivity; dft; bis(phosphinimino)methanides; stabilization |
| URI: | http://www.rsc.org/ej/CC/2008/b719633d.pdf
http://dx.doi.org/10.1039/b719633d
http://hdl.handle.net/1842/3016 |
| ISSN: | 1359-7345 |
| Appears in Collections: | Chemistry publications
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