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http://hdl.handle.net/1842/3014
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| Title: | An unsupported transition metal-lanthanide bond; synthesis and crystal structure of an Nd-Fe amido N-heterocyclic carbene complex |
| Authors: | Arnold P.L.
McMaster J.
Liddle S.T. |
| Issue Date: | 1-Jan-2009 |
| Citation: | Arnold P.L., McMaster J., Liddle S.T.. (2009-01-01) An unsupported transition metal-lanthanide bond; synthesis and crystal structure of an Nd-Fe amido N-heterocyclic carbene complex, Chemical Communications 7 818-820 |
| Abstract: | A salt-elimination reaction between the neodymium monoiodide [Nd(L)(N)(I)]2 [L = ButNCH2CH2{C(NCSiMe3CHNBut)}; N = N(SiMe3)2] and K[FeCp(CO)2] affords the first complex with an unsupported 4f–3d metal–metal bond that is sufficiently stable to be isolated; the bond is identified as principally ionic in nature by DFT calculations. |
| Keywords: | donor-acceptor bonds; element thermochemistry; coordination chemistry; disruption enthalpies; molecular-structure; actinide; ligands; reactivity; catalysts; titanium |
| URI: | http://www.rsc.org/ej/CC/2009/b819072k.pdf
http://dx.doi.org/10.1039/b819072k
http://hdl.handle.net/1842/3014 |
| ISSN: | 1359-7345 |
| Appears in Collections: | Chemistry publications
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